I took an industrial job out of grad school. An old-timer told me about a plant where the foreman of the night shift got better yields than anyone else. Nobody understood why. So they hired a private eye to work as a janitor and keep an eye on what the foreman was doing. Turned out he was peeing into the reactor.
I have heard much this same story, but it was that the operator or the janitor was spitting their chewing tobacco into the reactor...
Milkshake had a story on In The Pipeline about something similar in a CuSO4 plant in the Soviet Bloc, but there there was a mechanism that made sense (copper ammine complexes). I couldn't find the link (before 2013).
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